47. 16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings

Lutz, S.; Nattmann, L.; Nöthling, N.; Cornella, J. Organometallics 2021, 40, 2220–2230

Special Issue: Organometallic Solutions to Challenges in Cross-Coupling

46. Catalytic Activation of N2O at a Low-Valent Bismuth Redox Platform

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. J. Am. Chem. Soc. 2020, 142, 19473.

45. Dialkyl Ether Formation at High-Valent Nickel

Le Vaillant, F.; Reijerse, E.; Leutzsch, M.; Cornella, J. J. Am. Chem. Soc. 2020, 142, 19540

44. A Unified Strategy for Arylsulfur(VI) Fluorides from Aryl Halides: Access to Ar-SOF3 Compounds

Wang, L.; Cornella, J. Angew. Chem. Int. Ed. 2020, 59, 23510-23515

• Hot Paper in Angewandte Chemie International Edition.

43. Ni(4-tBu-stb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis

Nattmann, L.; Cornella, J. Organometallics 2020, 39, 3295

42. Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

Planas, O.; Peciukenas, V.; Cornella, J. J. Am. Chem. Soc. 2020, 142, 11382.

41. Synthesis of Sulfonyl Fluorides from Sulfonamides

Perez-Palau, M.; Cornella, J. Eur. J. Org. Chem. 2020, 2497

40. An Air-Stable Binary Ni(0)-Olefin Catalyst

Nattmann, L; Saeb, R.; Nöthling, N.; Cornella, J. Nature Catalysis 2020, 3, 6-13

• Highlighted in Nature Catalysis, News and Views, 2019 (Boit, T. B.; Spence, K. A.; Garg, N.K.)

• Highlighted in C&EN (Nickel catalyst fends off air attack).

• Highlighted in Org. Process. Res. Dev. 2020, 24, 115

• Highlighted in Nat. Rev. Chem. 2020, 4, 171.

39. Radical C-N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent.

Ma, Y.; Pang, Y.; Chabbra, S.; Reijerse, E. J.; Schnegg, A.; Niski, J.; Leutzsch, M.; Cornella, J. Chem. -Eur. J. 2020, 26, 3738-3743.

Previously in ChemRxiv 2019, doi: 10.26434/chemrxiv.11211245.v1

38. Pyrylium Salts: Selective Reagents for the Activation of Primary Amino Groups in Organic Synthesis

Pang, Y.; Moser, D. Cornella, J. SYNTHESIS 2020, 52, 489-503.

• Part of the Bürgenstock Special Edition 2019 Future Stars in Organic Chemistry

37. Facile Access to Chiral non-Natural Aminoacids

Planas, O.; Cornella, J. Nature Catalysis 2019, 2, 839. (News & Views Article)

36. Selective Late-Stage Sulfonyl Chloride Formation from Sulfonamides Enabled by Pyry-BF4

Gomez-Palomino, A.; Cornella, J. Angew. Chem. Int. Ed. 2019, 58, 18235-18239

• Highlighted in Organic Process Research and Development (OPR&D) Org. Process Res. Dev. 2019, 23, 2583−2591

35. Fluorination of Arylboronic Esters Enabled by Bismuth Redox Catalysis

Planas, O.; Wang, F.; Leutszch, M.; Cornella, J. Science, 2020, 367, 313-317.

Previously in ChemRxiv (doi.org/10.26434/chemrxiv.9729143.v1)

Abstract - Full text

• Highlighted in C&EN (Bismuth, often overlooked in the periodic table, breaks into redox catalysis).

• Highlighted in Organic Process Research and Development (OPR&D) 2020, 24, 323-333

• Highlighted in Synfacts 2020, 16, 409.

34. Bi(I)-catalyzed Transfer-Hydrogenation with Ammonia Borane

Wang, F.; Planas, O.; Cornella, J. J. Am. Chem. Soc. 2019, 141, 4235

• Highlighted in Chemistry Views - News March 2019.

• Highlighted in ChemBeanGo - April 2019 (available in chinese).

33. Ni-catalyzed Reductive Liebeskind-Srogl Alkylation of Heterocycles

Ma, Y.; Cammarata, J.; Cornella, J. J. Am. Chem. Soc. 2019, 141, 1918

• Highlighted in Synfacts, 2019, 15, 379

• Highlighted in Org. Process Res. Dev. 2019, 23, 289.

32. A Highly Reduced Ni-Li-Olefin Complex for Kumada-Corriu Cross-Couplings

Nattmann, L.; Lutz, S.; Ortsack, P.; Goddard, R. Cornella, J. J. Am. Chem. Soc. 2018, 140, 13628

31. A Perspective in Catalysis: Development of Efficient Methods in the Age of Sustainability

O'Neill, M. J.; Cornella, J. CHIMIA, 2018, 72, 601.

30. Retaining Alkyl Nucleophile Regiofidelity in Transition-Metal-Mediated Cross-Couplings to Aryl Electrophiles

O'Neill, M. J.; Cornella, J. SYNTHESIS, 2018, 50, 3974.

29. Selective Functionalization of Aminoheterocycles by a Pyrylium Salt

Moser, D.;* Duan, Y.;* Wang, F.; Ma, Y.; O'Neill, M. J.; Cornella, J. Angew. Chem. Int. Ed. 2018, 57, 11035.

• Highlighted in SynFacts, 2018, 14, 1123

28. Thorpe-Ingold Effect for Branch-Selective Alkylation of Unactivated Aryl Fluorides

O’Neill, M. J.;* Riesebeck, T.;* Cornella, J. Angew. Chem. Int. Ed. 2018, 57, 9103 (* equal contribution)

• Highlighted in SynFacts, 2018, 14, 967