64. Ni-Catalyzed Oxygen Transfer from N2O onto sp3‑Hybridized Carbons

Ni, S.; Le Vaillant, F.; Mateos,-Calbet, A.; Martin, R.; Cornella, J. J. Am. Chem. Soc. 2022, 144, 18223.

63. Mechanism of the Aryl‒F Bond-Forming Step from Bi(V) Fluorides

Planas, O.; Peciukenas, V.; Leutzsch, M.; Nöthling, N.; Pantazis, D.; Cornella, J. J. Am. Chem. Soc. 2022, 144, 14489.

62. Radical Activation of Ammonia and Water at Bismuth(II)

Yang, X.; Reijerse, E.; Bhattacharyya, K.; Leutzsch, M.; Kochius, M.; Nöthling, N.; Busch, J.; Schnegg, A.; Auer, A.; Cornella, J. J. Am. Chem. Soc. 2022, 144, 16535.

Previously on ChemRxiv: https://doi.org/10.26434/chemrxiv-2022-4rcdc

61. Constitutional isomerism in heterocycles: A structural revision of benzofused isothiazoles

Ghiazza, C.; Fernandez, S.; Leutzsch, M.; Cornella, J. Tetrahedron 2022, 120, 132888.

(In honor of Professor Dr Franziska Schoenebeck for the 2022 Tetrahedron Young Investigator Award in Organic Synthesis).

60. Synthesis and Structure of Mono-, Di-, and Trinuclear Fluorotriarylbismuthonium Cations

Kuziola, J.; Magre, M.; Nöthling, N.; Cornella, J. Organometallics 2022, 41, 1754–1762

59. Catalytic synthesis of phenols with nitrous oxide

Le Vaillant, F.; Mateos Calbet, A.; Rodriguez-Pelayo, S.; Reijerse, E. J.; Ni, S.; Busch, J.; Cornella, J. Nature, 2022, 604, 677-683.

58. (Hetero)aryl-S(VI)-Fluorides: Synthetic Development and Opportunities

Magre, M.; Ni, S.; Cornella, J. Angew. Chem. Int. Ed. 2022, 61, e202200904

57. Deaminative Chlorination of Aminoheterocycles

Ghiazza, C.; Faber, T.; Gómez-Palomino, A.; Cornella, J. Nat. Chem. 2022, 14, 78-84.

previously on ChemRxiv (link)

56. Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis

Moon, H. -W.; Cornella, J. ACS. Catal. 2022, 12, 1382-1393.

55. Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides

Magre, M.; Cornella, J. J. Am. Chem. Soc. 2021, 143, 21497−21502.

54. Tris[1,1′-[η2-(1E)-1,2-Ethenediyl]bis[4-(Trifluoromethyl)Benzene]]Nickel

Saeb, R.; Cornella, J. Encyclopedia of Reagents for Organic Synthesis, (EROS) online asap.

53. Organometallic Compounds of Arsenic, Antimony and Bismuth

Pang, Y.; Cornella, J. Organometallic Compounds of Arsenic, Antimony and Bismuth, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2021 (book chapter)

52. Air-Stable tris-(stilbene)Ni(0) Complexes

Saeb, R.; Cornella, J. STREM Chemiker. 2021, vol. XXXII, No 1, 1-14.

51. High-valent bismuth redox catalysis

Planas, O.; Cornella, J. Nachrichten aus der Chemie, 2021, 69, 79-83 (Perspective)

50. Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

Pang, Y.; Leutzsch, M.; Nöthling, N.; Katzenburg, F.; Cornella, J. J. Am. Chem. Soc. 2021, 143, 12487

49. Validation of Arylphosphorothiolates as Convergent Substrates for Ar-SF4Cl and Ar-SF5 Synthesis

Wang, L.; Ni, S.; Cornella, J. Synthesis, 2021, 53, 4308–4312

Special Issue dedicated to Prof. Sarah Reisman, recipient of the 2019 Dr. Margaret Faul Women in Chemistry Award

48. Dibismuthanes in Catalysis: from Synthesis and Characterization to Redox Behavior Towards Oxidative Cleavage of 1,2-diols

Magre, M.; Kuziola, J.; Nöthling, N.; Cornella, J. Org. Biomol. Chem. 2021, 19, 4922-4929

This article is part of the themed collections: p-Block Lewis Acids in Organic Synthesis and Catalysis & Biocatalysis in OBC

47. 16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings

Lutz, S.; Nattmann, L.; Nöthling, N.; Cornella, J. Organometallics 2021, 40, 2220–2230

Special Issue: Organometallic Solutions to Challenges in Cross-Coupling

46. Catalytic Activation of N2O at a Low-Valent Bismuth Redox Platform

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. J. Am. Chem. Soc. 2020, 142, 19473.

45. Dialkyl Ether Formation at High-Valent Nickel

Le Vaillant, F.; Reijerse, E.; Leutzsch, M.; Cornella, J. J. Am. Chem. Soc. 2020, 142, 19540